Use of Nb in place of V (2b/5)26 Mar 2021 05:05
(b) The effect of alloying elements on steel properties
see http://www.substech.com/dokuwiki/doku.php?id=effect_of_alloying_elements_on_steel_properties
Alloying is changing chemical composition of steel by adding elements with the purpose of improving its properties as compared to the plane carbon steel.
There are six principle properties of steel which can be modified by the addition of specific alloys:
* Stabilizing austenite: increasing the temperature range, in which austenite exists. Elements relevant: Ni, Mn, Co, Cu
* Stabilizing ferrite: decreasing the temperature range in which austenite exists. Elements relevant: Cr, W, Mo, V, Al, Si
* Carbide forming: elements forming hard/complex carbides, increasing steel hardness and strength. Elements relevant: Cr, W, Mo, V, Ti, Nb, Ta, Zr
* Graphitizing: decreasing stability of carbides, promoting their breaking and formation of free graphite. Elements relevant: Si, Ni, Co, Al
* Decrease of the eutectoid concentration. Elements relevant: Ti, Mo, W, Si, Cr, Ni
* Increase of corrosion resistance: elements form thin a strong oxide film on the steel surface, protecting it from chemical attacks. Elements relevant: Al, Si, and Cr
(c) Alternatively, we can summarise the characteristics of alloying elements:
Manganese (Mn): improves hardenability, ductility and wear resistance.
Nickel (Ni): increases strength, impact strength and toughness, impart corrosion resistance in combination with other elements.
Chromium (Cr): improves hardenability, strength and wear resistance, sharply increases corrosion resistance at high concentrations.
Tungsten (W): increases hardness particularly at elevated temperatures due to stable carbides, refines grain size.
Vanadium (V): increases strength, hardness, creep resistance and impact resistance due to formation of hard vanadium carbides, limits grain size.
Molybdenum (Mo): increases hardenability and strength particularly at high temperatures and under dynamic conditions.
Silicon (Si): improves strength, elasticity, acid resistance and promotes large grain sizes, which cause increasing magnetic permeability.
Titanium (Ti): improves strength and corrosion resistance, limits austenite grain size.
Cobalt Co: improves strength at high temperatures and magnetic permeability.
Zirconium (Zr): increases strength and limits grain sizes.
Boron (B): highly effective hardenability agent, improves deformability and machinability.
Copper Cu: improves corrosion resistance.
Aluminium (Al): deoxidizer, limits austenite grains growth.
In summary, while niobium (as well as tantalum) is a recognised carbide-forming element, and therefore contributes to steel's hardness and strength, the properties of steel are complex, and no simple substitution of one element by another can guarantee that the resulting properties of steel will meet the various and stringent requirements imposed by the construction industry.