RE: VRFB's6 Feb 2019 09:16
zeus - well naturally nothing happens to the electrolyte on year 20 + 1 day. It is most probably the power stacks that might need replacing at that point, plus probably some seal replacing as 'preventative maintenance' along the way. The electrolyte can simply be transferred to another battery - if it needs cleaning up at that stage to remove any bits of crud or impurity that may have got into it after 20 years of operation then this would likely be a simple filtering and chemical purification process, essentially the same as what might have needed to be applied as the last stage of electrolyte production on day 0.
I am a solid state physicist by training but I really like the VRFB approach because everything is in liquid form in the electrolyte.
This is very unlike an essentially solid state battery such as a lithium-ion battery where the operation depends upon the precise nature of the crystal and mesoscopic (larger than atoms but smaller than a few microns) scale which always breaks down over time and charge cycling. You could have all the right atoms in the wrong structure and you have no battery. Essentially all solid-state batteries are destroying themselves from day one, it's just that occasionally that you can come up with a structure that last a little longer than the others.
There is no justifiable reason to believe that a useful 20,000 cycle solid-state battery lies just around the corner when we can currently only get a few thousand cycles to work. Pretty much all VRFB manufacturers show performance of at least 20,000 cycles.