RE: Dr. Spencer of U3O8 Corp re Vanadiu13 Jul 2018 00:43
kevkan - well to be honest the key features that battery manufacturers are stressing is:
1) long life - 20 years. UET showed data from 275,000 cycles. Sumitomo presented real operational data for a 60MWh VRFB that has been running for over 6 years in all sorts of useful modes.
2) safety - UET pointed out that the New York Fire Department will not allow any energy storage in the city of New York that uses Lithium. It's not just the explosive nature of any Lithium-ion battery fires it's also the fluorine gas that would be liberated in a fire.
3) cost - once you take the lifetime of the battery correctly into account and do a Levelised cost of storage (LCOS) eg Lazard 3 calculation then VRFB's are already cost competitive with Lithium-ion
4) sublinear cost scaling for longer duration batteries - this is where the arguments seem to get overly complex but this is really the critical issue so I will go into it in detail.
At present most large scale batteries (even the Jamestown 129MWh one in Australia - Musk's claimed world's biggest) on the grid are essentially used as a power reserve for (sometimes called a spinning reserve because previously it was the spinning nature of all the turbines that acted as a short term energy store that would smooth out fluctuations in demand/supply) - these are fluctuations over a few minutes or so.
Lithium-ion batteries are fine for those types of timescales and you get to boast that you charged and discharged your battery lots of times in a day and so can earn money if your local grid pays you to provide a power reserve, which is the application that grids first came up with incentivisation payments for (so called enhanced frequency regulation.)
Another thing that grids imagine is the idea that the might be able to avoid having to build so called peaker plants that are usually open cycle gas turbines, so can be switched on and off quite quickly, but which are very inefficient. Using a battery instead of a peaker plant might require discharge timescales of 20-30 minutes, but it is still very early days and I'm not sure many grids have worked out exactly how they can pay people to build electrochemical peaker plants (which is fed with electricity instead of gas) in preference to good old fashioned gas ones that they've done for years.
However neither of those kinds of battery timescales are going to help you keep the lights on at 12 midnight if the sun went down at 8pm and with it your PV renewable source of energy. To use the energy that can be harvested during sunlight hours you need to store it for a good few hours (no problem pretty much all batteries can store energy for days without self-discharge leaking it away) but more importantly you need to have the ability to deliver huge energies at significant rates for many hours after sundown. Flow batteries are clearly the way to get long duration batteries with sublinear cost (double the duration of energy storage yis just double the electr