RE: Questions on large scale energy storage26 Aug 2019 11:40
Vauxhall Viva - my doctorate is in cryogenics so I should like these things.
However I don't - the reason for this is that compressing gas to make liquid cryogen liberates very large amounts of heat. Normally this is a problem and you simply chuck it away, because it s the cryogenic liquid that you want as you want to do something at the low temperatures that it provides. If you are using cryogenic liquids as a store of energy then you cannot afford to through the heat away as that would massively hurt your round trip efficiency - thus the problem becomes one of not just cryogenic storage but also heat storage, typically in some low cost material, like rocks.
The idea is that you bring the hot rocks back into contact with cryogenic liquid, generate high pressure gas which turns a turbine and you get your energy back. One concern is that this process ultimately causes great thermal stress on the rocks, making them break down, not in itself a major problem but it is powdered dust generated from this that would get carried to your turbines and which may end up wrecking them. The other concern that I have is the essential inefficiency in all cryogenic liquification systems - there is significant thermodynamic irreversibility in all liquification processes which ultimately will affect the round trip efficiency of any energy storage system that utilises such a gas-liquid phase transition. Thermodynamic efficiency is never really considered a priority in conventional liquifaction systems so I would be very wary about basing an energy storage revolution upon such an approach.
Finally I was discussing flow batteries with one of my contacts in the industry a few weeks ago - it seems that there was an InnovateUK competition a few years back that they had put together a GBP 15M flow battery application for but that this ultimately got trumped by the Highview power cryobattery. I had understood that these research grant competitions were meant to avoid civil servants having to 'pick winners', something that they have been loathe to do in the UK since the 1960's - however it seems that they have simply outsourced the picking of winners to someone else - in this case the innovateUK judging committee, however this is comprised.