Eureka18 Aug 2020 20:42
https://www.eurekalert.org/pub_releases/2020-08/mu-rcp081820.php
In 2020 China plans to launch the largest battery complex in the world with a capacity of 800 MW*h (approximately this amount of energy per year is consumed by a household with 200 apartments). This complex is based not on the usual lithium-ion or lead-acid batteries, but on the redox flow battery where the electricity is stored in the form of chemical energy of solutions - electrolytes. Battery consists of two tanks in which electrolytes are stored and membrane-electrode assembly (MEA) - solutions are supplied to MEA by pumps where they undergo electrochemical reactions which provide charging and discharging of the battery.
Due to this setup, redox flow batteries, unlike many other energy storage devices, enable independent scaling of power and capacity of the battery, which are determined by the size of MEA and electrolyte volume, respectively. In addition, redox flow batteries exhibit minimal self-discharge over extended periods and their electrolytes do not degrade even after tens of thousands of operating cycles, making them promising candidates for storing large amounts of energy in the smart power grids. For example, they can store excess electricity generated by photovoltaic solar cells during daylight and generate back-up electricity at night or in cloudy weather.
"Flow batteries are being actively integrated into the power grids of China, Germany and other countries, on one hand, and on the other hand, are continued to be developed and refined in laboratories", comments one of the authors of the work, researcher at the NTI Competence Center at IPCP RAS, Dmitry Konev. "We have proposed a completely new design of MEA, which will facilitate the research process and greatly reduce entrance threshold for new research groups into this area. In the future, this will help to achieve significant progress and will bring distributed energy resources from niche positioning to very high level of commercialization, including in Russia".
The MEA is the heart of the flow battery. It looks like a sandwich of different sheets materials, divided into two symmetrical parts supplied with its own electrolyte. When the battery is connected to a power supply, the one electrolyte is oxidized, while another is reducing and so the battery is charging. After that, the power source can be disconnected and replaced with energy consumer - the electrolytes will undergo reverse processes and the battery will begin to discharge.